Product ID:N-3507 ORANGE TREE MARKING
MSDS Date:04/30/1993
FSC:8010
NIIN:01-274-2568
MSDS Number: BVFNJ

NILES CHEMICAL PAINT CO

225 FORT ST
NILES, MI 49120
US

Emergency Phone: 616-683-3377 OR 219-236-5856

Info Phone: 616-683-3377 OR 219-236-5856

Preparer: MICHAEL LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

STODDARD SOLVENT

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 48%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM; 9394

ALKYD RESIN

Fraction By Weight: 21%

NAPHTHA, LIGHT AROMATIC (SOLVENT NAPHTHA)

CAS: 64742-95-6

RTECS: WF3400000

Fraction By Weight: 5-10% %

COBALT (SARA III),DUST AND FUME

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: <1%

OSHA PEL 0.1 MG/M3

ACGIH TLV: 0.05 MG/M3;DUST 9394

MANGANESE COMPOUNDS (SARA III)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: <1%

OSHA PEL C 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST 9394

PROPRIETARY MIXTURE

Fraction By Weight: BALANCE

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES- SEVERE IRRITATION AND BURNS.
SKIN- HARMFUL IF ABSORBED THROUGH SKIN. CAN BE ABSORBED IN TOXIC
AMOUNTS. INHALATION- NASAL AND RESPIRATORY IRRITATION, CNS
DEPRESSION. POSSIBLE UNCONSCIOUSNESS, E VEN ASPHYXIATION.
INGESTION- GASTROINTESTINAL IRRITATION AND EVEN DEATH.
Explanation of Carcinogenicity:PER MANUFACTURER.
Effects of Overexposure:EYES- LACRIMATION, REDNESS, BLURRED VISION,
VISUAL DISTURBANCES. INHALATION- DIZZINESS, DROWSINESS, WEAKNESS,
FATIQUE, CONFUSION, NAUSEA, HEADACHE, VERTIGO. INGESTION-
ABDOMINAL PAIN, NAUSEA, VOMITI NG, DIARRHEA, BLINDNESS.
Medical Cond Aggravated by Exposure:NONE KNOWN.

First Aid:INHALATION- MOVE VICTIM TO FRESH AIR AT ONCE. PERFORM
ARTIFICIAL RESPIRATION IF NEEDED. GET MEDICAL ATTENTION AS SOON AS
POSSIBLE. SKIN- WASH WITH SOAP AND WATER. EYES- IMMEDIATELY FLUSH
WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MIN, OCCASIONALLY
LIFTING UPPER AND LOWER LIDS. GET IMMEDIATE MEDICAL ATTENTION.
INGESTION- INDUCE VOMITING IMMEDIATELY. GET MEDICAL ATTENTION
IMMEDIATELY.

Flash Point Method:TCC
Flash Point:102F,39C
Lower Limits:0.8
Upper Limits:36.0
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WITH A
FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE AND FULL
PROTECTIVE CLOTHING. COOL CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, SPARKS, ELECTRICAL EQUIPMENT, AND OPEN FLAME. CLOSED
CONTAINERS MAY EXPLODE WHEN EXPOSED TO HIGH TEMPERATURE.

Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. MINIMIZE THE
BREATHING OF VAPORS AND AVOID SKIN CONTACT. ABSORB WITH AN INERT
MATERIAL SUCH AS CLAY, SOIL, OR A COMMERCIALLY AVAILABLE ABSORBENT.
SHOVEL RECLAIMED LIQUI D AND ABSORBENT INTO RECOVERY OR SALVAGE
DRUMS.

Handling and Storage Precautions:AVOID STORAGE IN HIGH TEMPERATURE
AREAS OR NEAR FIRE OR OPEN FLAME. KEEP CONTAINERS CLOSED WHEN NOT
IN USE. AVOID ROUGH HANDLING.
Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTY. DO NOT WELD OR FLAME CUT ON EMPTY CONTAINERS. *LARGE SPILLS:
DIKE TO PREVENT FURTHER MOVEMENT AND RECLAIM INTO RECOVERY OR
SALVANE DRUMS OR TAN K TRUCK FOR DISPOSAL.

Respiratory Protection:WEAR AN APPROPRIATE (TYPE TC-23C-75) PROPERLY
FITTED HALF-MASK OR FULL FACEPIECE RESPIRATOR (NIOSH/MSHA) DURING
AND AFTER APPLICATION UNLESS AIR MONITORING DEMONSTRATES VAPOR/MIST
LEVELS ARE BELOW AP PLICABLE LIMITS.
Ventilation:SUFFICIENT VENTILATION IN VOLUME AND PATTERN SHOULD BE
PROVIDED TO KEEP THE AIR CONCENTRATION BELOW ACCEPTABLE LEVELS.
Protective Gloves:NITRILE OR VITON GLOVES.
Eye Protection:CHEMICCAL GOGGLES, SAFETY GLASSES.
Other Protective Equipment:FACE SHIELD IF NEEDED. CHEMICAL RESISTANT
CLOTHING AS NEEDED.
Work Hygienic Practices:REMOVE ANY CLOTHING THAT BECOMES WET (TO AVOID
FLAMMABILITY HAZARD) AND WASH BEFORE REUSE.
Supplemental Safety and Health
WASH HANDS BEFORE EATING, SMOKING OR USING RESTROOM. *NOTE: THIS MSDS
REPRESENTS A FORMULATION CHANGE. CHECK MSDS DATE TO MAKE CERTAIN
THAT THE CORRECT MSDS FOR YOUR PRODUCT IS BEING USED.

HCC:F4
Boiling Pt:B.P. Text:146-398F
Melt/Freeze Pt:M.P/F.P Text:N/N
Vapor Density:> AIR
Spec Gravity:0.990
Evaporation Rate & Reference:< ETHER
Solubility in Water:SOLUBLE
Appearance and Odor:LIQUID, ODOR OF SOLVENTS.
Percent Volatiles by Volume:69.92

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS AND OPEN FLAMES.
Hazardous Decomposition Products:CAN PRODUCE CARBON MONOXIDE AND/OR
CARBON DIOXIDE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL,
STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.